RESIN CHELATING & ADSORBEN

Resin chelating & adsorben

TFI-CLS594 Product Data Sheet
Technical Product Specification

TFI-CLS594

Bis-Picolylamine Chelating Resin for Selective Separation of Copper, Nickel, and Cobalt

Functional Group

Bis-Picolylamine

High Selectivity

Copper & Nickel over Ferric Iron (Fe3+) at pH < 2

Primary Application

PLS Extraction & Working Solution Recuperation

Product Overview

TFI-CLS594 is a specialized chelating resin featuring a bis-picolylamine functional group. Due to this specific functionality, the resin possesses exceptionally high affinity for cations such as copper, uranyl, nickel, zinc, cobalt, and others.

TFI-CLS594 exhibits remarkable selectivity for copper and nickel against ferric iron, even at strong acidity levels below pH 2. These properties make it ideal for extracting copper and nickel from pregnant leach solutions (PLS) generated during mineral processing. Additionally, it is widely utilized in plating, etching, and galvanic processes for the recuperation of working solutions.

Key Performance & Operational Notes

  • Selectivity Order (Sulfate Solution, pH 2):
    Cu >> Ni >> Fe(III) > Cd > Zn > Co >> Fe(II) >>> (Ca, Mg, Al)
  • Fractional Elution (Ni/Co Separation):
    After collective sorption of Ni and Co by TFI-CLS594, the metals can be separated sequentially:
    1. Elute Cobalt (Co) using 0.5N H2SO4
    2. Elute Nickel (Ni) using ≥1N H2SO4
  • Strong Copper Binding & Desorption: Complexation with copper is extremely robust, enabling recovery from concentrated sulfuric acid or complexed ligands (e.g., DETA). Copper can be desorbed using an ammonium hydroxide solution to yield a copper ammine complex.

Precautions & Handling Guidelines

Storage Resins should be stored in sealed containers or bags where temperature is above 0°C in dry conditions without exposure to direct sunlight.
Chemical Risk Do not mix ion exchange resin with strong oxidizing agents; otherwise it will cause violent reactions.
First Aid In case of eye contact with resins, rinse eyes immediately with plenty of water, and consult a specialist.
Physical Property Dry polymers will expand when wetted and may cause an exothermic reaction. Spilled materials may be slippery.
Disposal Material and samples must be disposed of according to local regulations.

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